Biomass tar is the bottleneck of biomass gasification, which not only is adverse to energy production but also brings severe environmental issues. https://www.selleckchem.com/products/gsk3787.html A scrubber with vegetable oil is considered as a low-cost but efficient approach for tar removal, but the effects of oil's properties on different tar absorptions were rarely reported. In this study, canola oil, palm oil, and pure oleic acid and linoleic acid, which are the main compounds of vegetable oils, were employed for absorptive removal of benzene, toluene, and phenol. The degree of unsaturation, average molecular weight, and average chain length of solvents were quantitatively characterized. A series of time and temperature-dependent absorption experiments were conducted, and the relationship between oils' properties and absorption performances was built. Results showed that pure oleic acid had the biggest absorption capacity for benzene and toluene due to the mono-unsaturated structure. Increasing the average molecular weight and chain length also enhanced tar absorption. Moreover, Grey relative analysis was employed to investigate the influence of each factor on tar absorption. The average molecular weight exerted the most significant influence on tar absorption in the tested temperature range whose comprehensive relevance coefficients reached the highest at 0.9810, 0.7669, and 0.7739 for benzene, toluene, and phenol, respectively. This study puts more attention on the nature of vegetable oils, and we hope to provide useful information for modulating a better oil-based scrubber medium and further enhancing tar absorptive removal.Coalbed is the carrier for coalbed methane (CBM) enrichment and migration. The pore structure characteristics of coal and their main geological controlling factors are critical to the exploration and development of CBM. In this paper, 20 coal samples were collected from eastern Yunnan and western Guizhou, China. Based on vitrinite reflectance, proximate analysis, maceral analysis, and low-temperature N2 adsorption/desorption (LT-N2GA) experiments, the hysteresis coefficient of low-temperature N2 desorption was proposed, the types of pore structure were identified, and the effects of coal facies and rank on the pore structure were revealed. The results show that the Ro,max values of the 20 coal samples are between 0.74 and 3.38%, which belong to medium- and high-rank coal. In the coal macerals, the vitrinite is mainly collodetrinite. The inertinite is dominated by semifusinite, and some coal samples contain exinite. The coal samples investigated can be divided into two types. Type A samples mainly contain openin controlling factor of the pore structure of type A coal samples, while the pore structure of type B coal samples are jointly controlled by TPI and coal rank. Type B coal samples are mainly located in Zhuzang and Laochang high-rank coal research areas, while the distribution of type A coal samples is mainly in other medium-high-rank coal research areas. These results will contribute to the exploration and development of CBM and also guide the study of pore structures of other unconventional gas reservoirs.Prior studies have shown that trifluoromethylarenes can be labeled in high molar activities (Am > 200 GBq/μmol) with positron-emitting carbon-11 (t1/2 = 20.4 min) by the reaction of the copper(I) derivative of [11C]fluoroform [11C]CuCF3, with several types of precursors, such as aryl iodides, arylboronic acids, and aryldiazonium salts. Nonetheless, these precursors can be challenging to synthesize, and in the case of diazonium salts, are unstable. Methods that reduce challenges in precursor preparation for the synthesis of [11C]trifluoromethylarenes are desirable to enhance possibilities for developing biologically relevant 11C-labeled compounds as radiotracers for biomedical imaging with positron emission tomography (PET). Here, we explored the production of no-carrier-added [11C]trifluoromethylarenes from commercially available primary aromatic amines through reactions of [11C]CuCF3 with diazonium salts that were generated in situ. Moderate to high isolated decay-corrected radiochemical yields (RCY) (32-84%) were obtained rapidly (within 2 min) for many para-substituted and meta-substituted primary aromatic amines bearing a halo, methoxy, thiomethyl, hydroxy, nitro, nitrile, carboxyl, ethylcarboxy, or trifluoromethyl substituent. Null to low RCYs (0-13%) were observed only for ortho bromo-, nitro-, or nitrile-substituted precursors. This new radiosynthetic method usefully expands options for producing PET radiotracers bearing a [11C]trifluoromethyl group, especially from aryl amine precursors.Dewaxed honeycomb powder (HCP) was used as a promising adsorbent for removal of malachite green (MG) from aqueous solution. Raw honeycomb was strategically dewaxed by petroleum ether, and the purified product was characterized by Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), pHzpc, and proximate analysis. A high uptake capacity (123 mg/g) was found at neutral pH. Experimental data follow pseudo-second-order kinetics (k2 as 0.45 × 10-2 g/min/mg, R2 = 0.986) and Langmuir isotherm with R2 0.999. Thermodynamic parameters suggested a spontaneous (ΔG = -26.28 kJ/mol) and exothermic (ΔH = -11.61 kJ/mol) process, which suggests increased randomness (ΔS = 0.0486 kJ/mol) at the solid-liquid interface during the adsorption process. The material can be regenerated by ordinary salt solution (1 M NaCl) and efficiently reused for three cycles with a minimal loss in efficiency. Adsorption mechanism is proposed to be a combination of electrostatic interaction and π-π stacking between aromatic units of HCP and MG. Abundant availability, possibility of wax commercialization, economic sustainability, and comprehensive waste management make HCP an ideal choice for dye decolorization.A liquid cathode glow discharge (LCGD) was developed as a low-power and miniaturized excitation source of atomic emission spectrometry (AES) for the determination of K, Na, Ca, and Mg in water samples from rivers and lakes. The discharge stability and parameter influencing the analytical performance of LCGD-AES were systematically examined. Moreover, the measurement results of water samples using LCGD-AES were verified by ion chromatography (IC). The results showed that the optimized operating parameters are a 660 V discharge voltage, pH = 1.0 HNO3 as the supporting electrolyte, and a 4.0 mL min-1 solution flow rate. High concentrations of some metals may interfere with the detection of Ca and Mg. Low-molecular-weight organic substances do not have a remarkable enhancement on signal intensity. With the addition of 0.5% cetyltrimethylammonium chloride (CTAC), the emission intensity of elements can enhance significantly. However, it is not used to further evaluate the analytical performance due to instability of plasma after adding CTAC.


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Last-modified: 2025-01-23 (木) 06:52:04 (26d)